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Beilstein J. Org. Chem. 2019, 15, 2076–2084, doi:10.3762/bjoc.15.205
Graphical Abstract
Scheme 1: Asymmetric α-photooxygenation of chiral aldehydes.
Scheme 2: α-Photooxygenation of β-substituted aldehydes.
Scheme 3: Synthesis and α-photooxygenation of 3,4-diphenylbutanal (1).
Scheme 4: Stereoselective α-photooxygenation of 3,4-diphenylbutanal (1) with 1O2.
Scheme 5: Schematic representation of the in situ methodology and preferred conformation of diols with Mo2 co...
Figure 1: ECD spectra of diols syn-6 and anti’-6 recorded a) with 19 in DMSO and b) in acetonitrile compared ...
Scheme 6: Asymmetric synthesis of 3,4-diphenylbutane-1,2-diol.